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That is a very subjective question. It completely depends on your play style. However the weapons that get the most attention are these two:

Maliwan Hellfire Maliwan Volcano

They both are fire elemntal weapons with x4 modifiers and a guarantee to ignite the target. They also have a chance to cause a larger explosion which will burn other targets around the shot. I feel that the Torgue Cobra is similar to if not better than the Volcano yet it gets very little attention.

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